박재홍 Jae Hong Park

DOI: Vol.27(No.2) 141-146, 2011

Loess, a natural clay, was evaluated as an adsorbent for the decolorization of Acid Orange II, an azo and reactive dye, from aqueous solution. Adsorption studies were performed at 30°C and the effect of reaction time, loess dosage, initial concentration, loess particle size, pH, agitation rate were investigated to determine the optimum operation conditions. The removal efficiencies of color were measured to evaluate the effectiveness of loess. From this study, it was found that optimal reaction time was 10 min. Color removal efficiencies of Acid Orange II were increased as higher loess dosage, initial concentration and agitation rate. However, color removal efficiencies decreased when pH is high and loess particle becomes large. Adsorption of Acid Orange II fitted to the pseudo-second-order rate kinetics more than first-order rate kinetics. Langmuir and Freundlich adsorption isotherm constants and correlation coefficients were calculated and compared. It was concluded that the adsorption data of Acid Orange II onto loess fitted to the Freundlich model more than Langmuir model.

Acid Orange 2, adsorption, Color, Loess

박상형 Sang Hyoung Park , 박창열 Chang Yeol Park , 유철상 Chul Sang Yoo

DOI: Vol.27(No.2) 147-158, 2011

This study analyzed the linkage characteristics between road runoff and the nearest streams in mountain regions using a discriminant analysis. The road-to-stream linkage is an important characteristic to evaluate whether the contaminant on road surface is transported directly into the nearby channel system. This study evaluated a total of 51 drainage outlets of mountain roads near the Soyanggang Dam. The linkage between road and stream, slope and width of road, and other information necessary for the discriminant analysis have been collected by in situ investigation and by analyzing the Digital Elevation Model. Finally, as independent variables in the discriminant analysis, the contributing road representing the road characteristics (similar to the runoff from the road drainage outlet) and the distance and slope of the connecting channel between road and nearest stream were selected. Among these three, the distance was found to have the highest discriminant power, the contributing road the lowest. Using the discriminant function derived, 40 out of 51 cases (78.4%) were correctly discriminated and the remaining 11 cases (21.6%) were wrongly discriminated. Reasons of wrongly discriminated cases were mainly due to change in drainage outlet direction, excessive runoff, change in road-to-stream path, etc. This result also indicates that the road-to-stream linkage can be introduced or prohibited by exactly the same way.

Contaminant, Discriminant, Drainage, Road-to-stream

한미덕 Mi Deok Han , 김지찬 Ji Chan Kim , 정욱진 Wook Jin Chung

DOI: Vol.27(No.2) 159-166, 2011

The use of land cover was sharply changed during 1975~2007 in the Kyungan watershed (561.12 km2). The changes occurred over an area of more than 227.65 km2 during the overall period at changing rates of 1.04% per year for water area, 1.79% per year for residential area, 2.99% per year for bare area, 3.03% per year for wetland area, 3.04% per year for grass area, 0.87% per year for forest and 2.32% per year for agriculture area. Water, residential, bare and wetland areas increased, while grass, forest and agriculture areas decreased during the last 32 years. BOD concentrations of representative sites for each sub-watershed continuously increased until the early 2000s as residential area increased with the highest discharged load, but decreased after the mid 2000s except upper Kyungan watershed. Such decline appears to be associated with the planning of Total Maximum Daily Load management for Gwangju city and expansion of waste water treatment plant. It is necessary to control land use/cover changes of the upper watershed and to prepare appropriate watershed management system for improvement in river environment including water quality, stream flow and bio-diversity.

Geographic Information System (GIS), Kyungan watershed, LULC change, TMDL management system, Water quality

권순동 Soon Dong Kwon

DOI: Vol.27(No.2) 167-177, 2011

Billions of barrels of briny produced water are generated in the United States every year during oil and gas production. The first step toward recovering or reusing this water is to remove the hazardous organics dissolved in the briny produced water. Biological degradation of hazardous volatile compound could be possible regardless of salinity if they were extracted from briny water. In the current work, the effectiveness of a vapor phase biofilter to degrade the gas-phase contaminants (benzene, toluene, ethylbenzene and xylenes, BTEX) extracted from briny produced water was evaluated. The performance of biofilter system responded well to short periods when the BTEX feed to the biofilter was discontinued. To challenge the system further, the biofilter was subjected to periodic spikes in inlet BTEX concentration as would be expected when it is coupled to a Surfactant-Modified Zeolite (SMZ) bed. Results of these experiments indicate that although the BTEX removal efficiency declined under these conditions, it stabilized at 75% overall removal even when the biofilter was provided with BTEX-contaminated air only 8 hours out of every 24 hours. Benzene removal was found to be the most sensitive to time varying loading conditions. A passive, granular activated carbon bed was effective at attenuating and normalizing the peak BTEX loadings during SMZ regeneration over a range of VOC loads. Field testing of a SMZ bed coupled with an activated carbon buffering/biofilter column verified that this system could be used to remove and ultimately biodegrade the dissolved BTEX constituents in briny produced water.

Biofilter, Briny produced water, BTEX, Surfactant-Modified Zeolite (SMZ)

양정석 Jeong Seok Yang , 손진식 Jin Sik Sohn , 강대수 Dae Su Kang

DOI: Vol.27(No.2) 178-187, 2011

National water supply, water resources available, the ratio of water supply to total water resources, and the ratio of water supply to available water resources were investigated to find global seawater desalination plant market for 163 nations. Water resources available per capita from 2007 to 2016, population in water scarcity region from 2011 to 2016, and the ratio of water scarcity population to total population were also analyzed for the countries. Annual percentage increase in total municipal drinking water capital expenditure and Annual percentage increase in total industrial water market were analyzed to predict the amount of water supply by use. 76 countries are suffering from water scarcity and 60 countries among the countries have coastal regions. Forty countries were selected by considering the considerable amount and highly increasing trend of water demand by use. Most countries show increasing trend of industrial water and 82 countries have more than 4% annual increasing rate for domestic water expense from 2008 to 2016 among 163 countries. Among the 76 water scarcity countries 16 countries were finally selected by considering expense prediction by use. Middle-east, east asia, pacific ocean, and west europe regions include most selected countries.

Global market development, Seawater desalination, Water demand by region, Water demand by use, Water scarcity

최정수 Jung Su Choi , 주현종 Hyun Jong Joo

DOI: Vol.27(No.2) 188-193, 2011

The effects of coagulants on the microorganisms when they are injected directly into the biological treatment facility for T-P removal have been easily observed from the results of past experiments. As such this study is set out to derive the effective plans for the coagulant dosage by analyzing the effects of the injected coagulant on the microbial activity during the chemical treatment for T-P removal. The research methods entailed the assessment of removal efficiency of T-P according to the coagulant dosage while changing the molar ration between Alum and influent phosphorus. At the same time Specific Oxygen Uptake Rate (SOUR) according to the coagulant dosage was measured. SOUR was used as a method for indirect assessment of the microbial activity according to the coagulant dosage. The results from the study showed that with the increase in the alum dosage, the removal efficiency T-P tended to increase. On the other hand, the increase in coagulant dosage resulted in the decrease in SOUR, which indicates the decrease in the microbial activity. Such reduction in the activity could be explained by the increase in the concentration of removal efficiency of TBOD5. Based on experiment results from the study, it is determined that coagulant dosage affects the microbial activity. Moreover, the indirect assessment on the microbial activity using SOUR is considered possible.

Alum, Effect of chemical addition, Phosphorus removal, Specific oxygen uptake rate

박영식 Young Seek Park

DOI: Vol.27(No.2) 194-199, 2011

This study has been carried out to evaluate the performance of PbO2 electrode for the purpose of degradation of N,N-Dimethyl-4-nitrosoaniline (RNO, indicator of OH radical), generation of ozone and decolorization of Rhodamine B (RhB) in water. The effect of the applied current (0.2~1.2 A), electrolyte type (NaCl, KCl and Na2SO4), electrolyte concentration (0.0~2.5 g/L) and solution pH (3~11) were evaluated. Experimental results showed that RhB and RNO removal were increased with the increase of current, NaCl dosage and decrease of pH. Ozone generation tendencies appeared with the almost similar to the RhB and RNO degradation, except of solution pH (Ozone generation was increased with increase of pH). Optimum current for RhB degradation and consumption of electric power was 1.0 A. The RhB degradation with Cl type electrolyte were higher than that with the sulfate type. Optimum NaCl dosage for RhB degradation was 1.0 g/L.

Current density, Dye oxidation, Electrolyte, Hydroxyl radical, PbO2 electrode

우영국 Young Gug Woo , 박은영 Eun Young Park , 전양근 Yang Kun Jeon , 정명숙 Myung Suk Jeong , 임재명 Jay Myung Rim

DOI: Vol.27(No.2) 200-209, 2011

The purpose of the study is to optimally manage sewage treatment plant with analysis of phosphorus contribution and improvement of water quality contributing rate in the effect of inflowing point of effluent and Pal-Dang lake after reducing T-P discharge from large scale public sewage treatment plant at upstream of Pal-Dang lake. Also, this study, for enforcement of T-P in effluent, plans optimal management of effluent T-P through examining propriety of environmental, technological, and economical aspect such as water quality standard of domestic and foreign T-P and related policy. In regarding optimal management of T-P discharged from public sewage treatment plant located in upstream of Pal-Dang lake, the study drew following conclusions. With the optimal management of public sewage treatment plant, it showed that a pollution level became higher in the order of Sumgang E in South-Han river, C in Dalcheon, B1·B2, A in North-Han river, and J in Kyungancheon, and it is required reduction of T-P first. The highest value in analysis of benefit-costs from sewage treatment plant in the selected research area was Kyungan B, and the others are with the order of Jojong A, Bokha A, Kyungan A, and Yanghwa A. With result of this study, all 14 areas are required more enforced phosphorus treatment. The study resulted that the most top priority areas were Hangang F, Sumgang B, and Gyungan A, top priority areas were Bokha A, Dalcheon B, and Cheongmi A, priority areas were Hangang E, Heukcheon A, Gyungan B, and Jojong A, and potential areas were Sumgang A, Yanghwa A, Dalcheon A, and Hangang D. It seems to be appropriate to apply 0.2 mg/L of T-P treatment for water supply source reservation, 0.5 mg/L for the other areas by locally, and 0.2~0.5 mg/L for biological nitrogen·phosphorus treatment method and 0.5~1 mg/L for Conventional Activated Sludge by technologically. Also, it may be appropriate to apply 0.2 mg/L for the most top priority area(I), 0.3 mg/L for the top priority area(II), 0.4 mg/L for priority area(III), and 0.5 mg/L for potential area(IV) by the separation of priority area.

Optimal management of T-P, Optimal management of watershed, Pal-Dang Lake, Public sewage treatment plant, T-P contribution rate

조인준 In Jun Cho , 오상한 Sang Han Oh , 이상욱 Sang Wook Lee , 손창호 Chang Ho Son , 정의준 Wui Jun Chung

DOI: Vol.27(No.2) 210-217, 2011

In results of accomplishing fundamental study to improve the flocculant-mixing of the Flash-Mixer in Onsan Water-Treatment Plant at the small cost, We obtained 8.9% of mixing-efficiency from the field data and 3.2% of the characteristic flow-ratio as the available maximum volume-ratio in this Water-Treatment Plant. The optimum elements with the deflector diameter of 400 mm and deflector angle of 145° at the flow ratio of 3.2% could be obtained from the expanded study on the ground of the fundamental study. Finally, the efficiency could be improved about 510% from 8.9% to 45.4% and the average turbidity could be improved about 14%.

CFD, Field-data, Flow-Ratio, Mixing-Efficiency, Mixing-Strength, Zeta-Potential

강원구 Won Gu Kang , 정은성 Eun Sung Chung , 이길성 Kil Seong Lee

DOI: Vol.27(No.2) 218-227, 2011

The objective approach for assessment of stream naturalness is an essential part of the stream restoration project. This study proposes the methodology for the assessment of stream naturalness considering physical, biological and chemical factors. Physical factors consists of riffle and pool, river bed material, bank protection, floodplain vegetation and levee materials; biological factors are benthic macroinvertebrate, KSI (Korean Saprobic Index), and IBI (Index of Biological Integrity) and chemical factors are pH, DO (dissolved oxygen), and TP (total phosphorus). This procedure is applied to the Mokgamcheon. As a result, the downstream of Mokgamcheon (zone I) needs the prompt improvement of stream naturalness, compared to the others (zone II and III). This evaluation technique will be an effective tool to quantify the stream naturalness and can be used to set the target of stream restoration project.

Assessment of stream naturalness, Biological factor, Chemical factor, Physical factor

정우혁 Woo Hyeuk Jung , 이상진 Sang Jin Yi , 김건하 Geon Ha Kim , 정상만 Sang Man Jeong

DOI: Vol.27(No.2) 228-234, 2011

The goal of water quality management on stream and watershed is to focus not on discharged loads management but on a water quality management. Discharged loads management is not goal of water quality management but way for perform with total maximum daily loads management. It is necessary to estimate the relation between non-point source with stromwater runoff (NPSSR) and water quality to select a watershed where it is required to manage NPSSR for water quality improvement. To evaluate the effects of NPSSR on stream``s water quality, we compare the aspects of water quality in dry and wet seasons using flow duration curve analysis based on flow rate variation data by actual surveying. In this study we attempt to quantify the variation characteristic of water quality and estimate the Inflow characteristic of pollution source with water quality and flow rate monitoring on 10 watersheds. We try to estimate water quality and flow rate by regression analysis and try again regression analysis with each high and low water quality data more than estimations. An analysis of relation between water quality and flow rate of 10 watersheds shows that the water quality of the Nonsan and the Ganggyeong streams had been polluted by NPSSR pollutants. Other eight streams were important point source more than NPSSR. It is wide variation range of BOD5 also high average concentration of BOD5. We have to quantify water quality variation by cv1 in wet season and cv365 in dry season with comparing the estimate of high water quality and low water quality. This method can be used to indicator for water quality variation according to flow rate.

Flow regime alteration, Non-point source, Stormwater runoff, Total maximum daily Loads, Water quality variation, Watershed management

박종부 Jong Bu Park

DOI: Vol.27(No.2) 235-241, 2011

This study was performed to investigate the characteristics of nutrient removal of municipal wastewater in the submerged membrane bioreactor by addition of alum directly into aerobic tank. Membrane bioreactor consists of three reactors such as two intermittent anaerobic tanks and the aerobic tank with hollow fiber membrane. The removal efficiencies of CODCcr, BOD, SS, TN and TP on the membrane bioreactor were 94.0%, 99.1%, 99.9%, 66.9%, and 58.9%, respectively. In addition, The removal efficiencies of CODcr, BOD, SS, TN and TP on the membrane bioreactor with alum addition were 93.4%, 99.0%, 99.9%, 63.2%, and 96.8%, respectively. There was little difference between them on the nutrient removal efficiencies except phophorus removal. The estimated sludge production, specific denitrification rate, specific nitrification rate and phosphorus removal content on the membrane bioreactor were 1.76 kgTSS/d, 0.055 mgNO3-N/mgVSS·d, 0.031 mgNH4-N/mgVSS·d, and 0.095 kgP/d, respectively. And The estimated sludge production, specific denitrification rate, specific nitrification rate and phosphorus removal content on the membrane bioreactor with alum addition were 2.90 kgTSS/d, 0.049 mgNO3-N/mgVSS·d, 0.030 mgNH4-N/mgVSS·d, and 0.160 kgP/d, respectively. The alum content added was 1.7 molAl/molP on an average. The increasing ratio of tran-membrane pressure on the membrane bioreactor was 0.0056 kgf/cm2·compared to 0.0033 kgf/cm2·d on the membrane bioreactor with alum addition. There was a slightly reduction effect on membrane fouling by alum addition.

Alum, Hollow fiber, Membrane bioreactor, Nutrient removal